The fashion bible also shared more amazing snaps from the gorgeous shoot with the pop star.
During an interview with the publication, Dion, 49, discusses her love for couture wear and makes a sentimental statement about her late husband Rene.
She tells Vogue that her collection of jewellery is more than just aesthetic pieces.
"Sometimes, when she is at home in Las Vegas and missing her partner Rene, she slips on a caftan and all her jewels, and quietly retreats to her bath, sans children, sans fans, sans circus," the Magazine captioned a snap of Dion.
Bless! Her heart truly will go on.